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dc.contributor.advisorMauler, Raquel Santospt_BR
dc.contributor.authorSouza, Claudio Roberto Lima dept_BR
dc.date.accessioned2021-01-20T04:18:44Zpt_BR
dc.date.issued2020pt_BR
dc.identifier.urihttp://hdl.handle.net/10183/217478pt_BR
dc.description.abstractThermoplastic foams nowadays are widely used in a variety of applications, such as packaging, construction, and the automotive industry because of their wide range of properties such as lightweight, excellent strength/weight ratio, insulation properties, energy absorption performance, and material cost. However, there are still issues on the gas barrier and mechanical properties in use because of the cellular structure. This work targeted to unveil the processing-structure-property relationships of three film/foam multilayer polymeric systems with diverse transport properties. The first part of the thesis (Chapter 2) focuses on the understanding of the effect of the number of layers and composition on mechanical properties and barrier properties of multilayer film/foam material with alternating ethylene-vinyl alcohol copolymer (EVOH) film layers and low-density polyethylene (LDPE) foam layers. Tensile properties of the film/foams at elevated temperatures were used to optimize thermoforming conditions. Uniaxial orientation was discovered as an efficient approach to evaluate the potential for thermoforming. Oxygen transmission showed a strong correlation with the thickness reduction which could be used as an indicator for barrier properties of the packaging materials. Film/foam materials with 32 layers demonstrated optimum performance with low oxygen transmission along with high drawing capability. In the third chapter, the previous system (Chapter 2) was innovated with high-density polyethylene (HDPE) skin layer. High oxygen and water vapor barrier film/foam system had been developed using multilayer co-extrusion technology. The film/foams contained alternating low-density polyethylene (LDPE) foam layers and ethylene–vinyl alcohol (EVOH) copolymer film layers with HDPE skin layer. The lightweight film/foams showed oxygen and water vapor transmission rate are correlated with the EVOH film layer and HDPE skin layer composition. The layered film/foam was successfully thermoformed at 80 °C with low oxygen transmission along with high drawing capability. The fourth chapter introduces a novel approach, to produce PLA/PLA multilayer film/foams structures having 16, 32, and 64 alternating layers. The lightweight multilayered PLA/PLA film/foam has a unique solid/porous alternating horizontal architecture, in which the film layers can effectively control the growth of the cells and suppress the premature rupture of cells during coextrusion process. Tensile properties at elevated temperatures of the PLA film were used to optimize thermoforming conditions. The effects of annealing temperature and time on the crystallinity and oxygen permeability of PLA/PLA multilayer film/foams were investigated. Oxygen transmission showed a strong correlation with the crystallinity of PLA/PLA multilayer film/foam. The material demonstrated high performance with low oxygen transmission which could be used as high barrier material.en
dc.format.mimetypeapplication/pdfpt_BR
dc.language.isoengpt_BR
dc.rightsOpen Accessen
dc.subjectMultilayer filmsen
dc.subjectPolipropilenopt_BR
dc.subjectFoam systemsen
dc.subjectEspumaspt_BR
dc.subjectCopolímerospt_BR
dc.subjectThermoplastic foamsen
dc.subjectGas barrieren
dc.titleStructure-property relationships in high barrier multilayer film/foam systemspt_BR
dc.typeTesept_BR
dc.contributor.advisor-coWnek, Gary E.pt_BR
dc.identifier.nrb001120917pt_BR
dc.degree.grantorUniversidade Federal do Rio Grande do Sulpt_BR
dc.degree.departmentInstituto de Químicapt_BR
dc.degree.programPrograma de Pós-Graduação em Químicapt_BR
dc.degree.localPorto Alegre, BR-RSpt_BR
dc.degree.date2020pt_BR
dc.degree.leveldoutoradopt_BR


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