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dc.contributor.authorLeger, Jean Michelpt_BR
dc.contributor.authorTomaszewski, P.E.pt_BR
dc.contributor.authorAtouf, A.pt_BR
dc.contributor.authorPereira, Altair Soriapt_BR
dc.date.accessioned2014-10-07T02:11:28Zpt_BR
dc.date.issued1993pt_BR
dc.identifier.issn0163-1829pt_BR
dc.identifier.urihttp://hdl.handle.net/10183/104228pt_BR
dc.description.abstractAngular-dispersive x-ray in situ powder-diffraction experiments have been performed on pure zirconia, Zr02, at room temperature under high pressure up to 50 GPa. Under increasing pressure four phases were successively encountered: baddeleyite (monoclinic, P21/c) from normal pressure up to about 10 GPa, orthorhombic-1 (Pbca) to 25 GPa, orthorhombic-11 to 42 GPa, and orthorhombic-111 above 42 GPa. The unit-cell parameters and the volume have been determined as a function ofpressure. The bulk moduli of the two lower pressure phases have been calculated using Birch's equation of state. The bulk modulus of baddeleyite, 95 GPa, is much lower than expected from bu1k modulus-volume systematics, 195 GPa, while for the orthorhombic-1 phase, the experimental and calculated values are almost identical. A generalized P-T diagram for Zr02, including an orthorhombic-IV phase, is proposed and discussed. The phase transition to orthorhombic-11 and orthorhombic-111 phases can be described by a simple rotation of the unit cell of the orthorhombic-1 phase about either the b axis to form the orthorhombic-11 phase or a axis to form the orthorhombic-111 phase. All high-pressure cells (orthorhombic-1, -11, and -111) have eight formula units (Z =8). The orthorhombic-11 phase was found not to have the cotunnite PbC12-type structure which was proposed previously. There is no longer any examp1e of a compound which transforms to such a cotunnite-type structure under high pressure. The behavior of zirconia and hafnia under high pressure is different although they have very close chemical properties at ambient pressure and identical structures in the two lower-pressure phases.en
dc.format.mimetypeapplication/pdf
dc.language.isoengpt_BR
dc.relation.ispartofPhysical review. B, Condensed matter. New York. Vol. 47, no. 21 (June 1993), p. 14075-14083pt_BR
dc.rightsOpen Accessen
dc.subjectFísica da matéria condensadapt_BR
dc.subjectAltas pressõespt_BR
dc.subjectMateria condensadapt_BR
dc.subjectFisica de altas pressoespt_BR
dc.subjectDifração de raios Xpt_BR
dc.subjectZircôniapt_BR
dc.titlePressure-induced structural phase transitions in zirconia under high pressurept_BR
dc.typeArtigo de periódicopt_BR
dc.identifier.nrb000256706pt_BR
dc.type.originEstrangeiropt_BR


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