Polypyrrole/ionic liquid/Au nanoparticle counter-electrodes for dye-sensitized solar cells : improving charge-transfer resistance at the CE/electrolyte interface
dc.contributor.author | Loguercio, Lara Fernandes | pt_BR |
dc.contributor.author | Matos, Carolina Ferreira de | pt_BR |
dc.contributor.author | Oliveira, Matheus Costa de | pt_BR |
dc.contributor.author | Marin, Graciane | pt_BR |
dc.contributor.author | Khan, Sherdil | pt_BR |
dc.contributor.author | Dupont, Jairton | pt_BR |
dc.contributor.author | Teixeira, Sergio Ribeiro | pt_BR |
dc.contributor.author | Balzaretti, Naira Maria | pt_BR |
dc.contributor.author | Ferreira, Jacqueline | pt_BR |
dc.contributor.author | Santos, Marcos José Leite | pt_BR |
dc.date.accessioned | 2022-10-03T04:48:37Z | pt_BR |
dc.date.issued | 2019 | pt_BR |
dc.identifier.issn | 0013-4651 | pt_BR |
dc.identifier.uri | http://hdl.handle.net/10183/249551 | pt_BR |
dc.description.abstract | To provide a viable alternative for counter electrodes used in dye sensitized solar cells, polypyrrole (PPy) based films have been synthesized via electrochemical deposition in the presence of the ionic liquid 1-butyl-3-methylimidazolium bis-(trifluoromethanesulfonyl) imidate (NTf2) and incorporated with gold nanoparticles (Aunanop). The films were analyzed by SEM, UV-Vis-NIR, Raman, Electrochemical impedance spectroscopy, Cyclic voltammetry and Conductivity measurements. The presence of the ionic liquid is found to result in a more conductive film, to improve catalytic reduction of I3 − and the electrochemical reversibility of the electrode. In addition to increase conductivity, impedance spectroscopy has shown that incorporating Aunanop in the PPy/NTf2 film helps improving the interfacial charge transportation, the electrocatalytic properties and solar energy conversion efficiency. DSSCs assembled with PPy based CE presented nearly the same J-V characteristic parameters as observed from conventional Pt based device | en |
dc.format.mimetype | application/pdf | pt_BR |
dc.language.iso | eng | pt_BR |
dc.relation.ispartof | Journal of the Electrochemical Society. Hooksett. Vol. 166, no. 5 (Jan. 2019), p. H3188-H3194 | pt_BR |
dc.rights | Open Access | en |
dc.subject | Celulas solares fotoquimica | pt_BR |
dc.subject | Conversão fotovoltaica | pt_BR |
dc.subject | Semicondutores | pt_BR |
dc.subject | Fotoeletroquímica | pt_BR |
dc.subject | Conversão de energia | pt_BR |
dc.subject | Líquido iônico | pt_BR |
dc.subject | Polipirrol | pt_BR |
dc.subject | Nanopartículas | pt_BR |
dc.title | Polypyrrole/ionic liquid/Au nanoparticle counter-electrodes for dye-sensitized solar cells : improving charge-transfer resistance at the CE/electrolyte interface | pt_BR |
dc.type | Artigo de periódico | pt_BR |
dc.identifier.nrb | 001105804 | pt_BR |
dc.type.origin | Estrangeiro | pt_BR |
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