The double-layer of penetrable ions : an alternative route to charge reversal
dc.contributor.author | Frydel, Derek | pt_BR |
dc.contributor.author | Levin, Yan | pt_BR |
dc.date.accessioned | 2020-01-30T04:10:03Z | pt_BR |
dc.date.issued | 2013 | pt_BR |
dc.identifier.issn | 0021-9606 | pt_BR |
dc.identifier.uri | http://hdl.handle.net/10183/205131 | pt_BR |
dc.description.abstract | We investigate a double-layer of penetrable ions near a charged wall. We find a new mechanism for charge reversal that occurs in the weak-coupling regime and, accordingly, the system is suitable for the mean-field analysis. The penetrability is achieved by smearing-out the ionic charge inside a sphere, so there is no need to introduce non-electrostatic forces and the system in the low coupling limit can be described by a modified version of the Poisson-Boltzmann equation. The predictions of the theory are compared with the Monte Carlo simulations. | en |
dc.format.mimetype | application/pdf | pt_BR |
dc.language.iso | eng | pt_BR |
dc.relation.ispartof | The journal of chemical physics. New York. Vol. 138, no. 17 (May 2013), 174901, 8 p. | pt_BR |
dc.rights | Open Access | en |
dc.subject | Camadas adsorvidas | pt_BR |
dc.subject | Adsorção | pt_BR |
dc.subject | Carregamento de superfície | pt_BR |
dc.title | The double-layer of penetrable ions : an alternative route to charge reversal | pt_BR |
dc.type | Artigo de periódico | pt_BR |
dc.identifier.nrb | 000900451 | pt_BR |
dc.type.origin | Estrangeiro | pt_BR |
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