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dc.contributor.authorLevin, Yanpt_BR
dc.date.accessioned2020-01-28T04:11:06Zpt_BR
dc.date.issued2000pt_BR
dc.identifier.issn0021-9606pt_BR
dc.identifier.urihttp://hdl.handle.net/10183/204973pt_BR
dc.description.abstractA theory is presented to account for the increase in surface tension of water in the presence of electrolyte. Unlike the original “grand-canonical” calculation of Onsager and Samaras, which relied on the Gibbs adsorption isotherm and led to a result which could only be expressed as an infinite series, our approach is “canonical” and produces an analytic formula for the excess surface tension. For small concentrations of electrolyte, our result reduces to the Onsager–Samaras limiting law.en
dc.format.mimetypeapplication/pdfpt_BR
dc.language.isoengpt_BR
dc.relation.ispartofThe journal of chemical physics. New York. Vol. 113, n. 21 (Dec. 2000), p. 9722-9726pt_BR
dc.rightsOpen Accessen
dc.subjectAdsorçãopt_BR
dc.subjectEletrólitospt_BR
dc.subjectTensão superficialpt_BR
dc.titleInterfacial tension of electrolyte solutionspt_BR
dc.typeArtigo de periódicopt_BR
dc.identifier.nrb000284606pt_BR
dc.type.originEstrangeiropt_BR


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