Diastereosseletividade na redução de enonas bicíclicas com hidretos volumosos
dc.contributor.author | Camozzato, Andreza Casanova | pt_BR |
dc.contributor.author | Tenius, Beatriz Soares Machado | pt_BR |
dc.contributor.author | Oliveira, Eduardo Rolim de | pt_BR |
dc.contributor.author | Viegas Junior, Claudio | pt_BR |
dc.contributor.author | Victor, Mauricio Moraes | pt_BR |
dc.contributor.author | Silveira, Leandro Greff da | pt_BR |
dc.date.accessioned | 2013-07-02T01:43:16Z | pt_BR |
dc.date.issued | 2008 | pt_BR |
dc.identifier.issn | 0100-4042 | pt_BR |
dc.identifier.uri | http://hdl.handle.net/10183/72873 | pt_BR |
dc.description.abstract | Reduction of five substituted octalones employing lithium tri-sec-butylborohydride (L-selectride®) in THF and ethyl ether led to allylic alcohols with moderate diastereoselectivity. The stereoselectivity of addition of bulky hydrides showed to be different from most examples in the literature and was strongly influenced by substitution on the octalone ring. | en |
dc.format.mimetype | application/pdf | pt_BR |
dc.language.iso | por | pt_BR |
dc.relation.ispartof | Química nova. São Paulo. Vol. 31, n. 4 (jun. 2008), p. 793-797 | pt_BR |
dc.rights | Open Access | en |
dc.subject | Octalones | en |
dc.subject | Enquadramento sindical : Brasil | pt_BR |
dc.subject | Enonas : Redução diastereosseletiva | pt_BR |
dc.subject | Reduction | en |
dc.subject | L-selectride® | en |
dc.subject | Síntese orgânica | pt_BR |
dc.title | Diastereosseletividade na redução de enonas bicíclicas com hidretos volumosos | pt_BR |
dc.title.alternative | Diastereoselectivity in the reduction of bicyclic enones with hindered hydrides | en |
dc.type | Artigo de periódico | pt_BR |
dc.identifier.nrb | 000682593 | pt_BR |
dc.type.origin | Nacional | pt_BR |
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