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dc.contributor.authorSantos, Alexandre Pereira dospt_BR
dc.contributor.authorDiehl, Alexandrept_BR
dc.contributor.authorLevin, Yanpt_BR
dc.date.accessioned2020-01-30T04:09:21Zpt_BR
dc.date.issued2010pt_BR
dc.identifier.issn0021-9606pt_BR
dc.identifier.urihttp://hdl.handle.net/10183/205083pt_BR
dc.description.abstractA theory is proposed which allows us to self-consistently calculate the effective colloidal charge and the counterion and coion density profiles in suspensions containing both multivalent and monovalent electrolytes. The formation of counterion-coion clusters is explicitly taken into account. The theory predicts that sufficiently strongly charged colloidal particles will become overcharged. The addition of monovalent electrolyte decreases the counterion condensation and diminishes the amount of charge reversal. Predictions of the theory are compared with the Monte Carlo simulations and are found to be in excellent agreement without any adjustable parameters.en
dc.format.mimetypeapplication/pdfpt_BR
dc.language.isoengpt_BR
dc.relation.ispartofThe journal of chemical physics. New York. Vol. 132, no. 10 (Mar. 2010), 104105, 5 p.pt_BR
dc.rightsOpen Accessen
dc.subjectMecânica estatísticapt_BR
dc.subjectColóidespt_BR
dc.subjectEletrólitospt_BR
dc.subjectPartículaspt_BR
dc.subjectTeoria funcional de densidadept_BR
dc.subjectSuspensoespt_BR
dc.subjectMétodo de Monte Carlopt_BR
dc.titleColloidal charge renormalization in suspensions containing multivalent electrolytept_BR
dc.typeArtigo de periódicopt_BR
dc.identifier.nrb000735980pt_BR
dc.type.originEstrangeiropt_BR


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