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dc.contributor.authorColla, Thiago Escobarpt_BR
dc.contributor.authorSantos, Alexandre Pereira dospt_BR
dc.contributor.authorLevin, Yanpt_BR
dc.date.accessioned2020-01-30T04:09:11Zpt_BR
dc.date.issued2012pt_BR
dc.identifier.issn0021-9606pt_BR
dc.identifier.urihttp://hdl.handle.net/10183/205068pt_BR
dc.description.abstractThe thermodynamic properties of highly charged colloidal suspensions in contact with a salt reservoir are investigated in the framework of the renormalized Jellium model (RJM). It is found that the equation of state is very sensitive to the particular thermodynamic route used to obtain it. Specifically, the osmotic pressure calculated within the RJM using the contact value theorem can be very different from the pressure calculated using the Kirkwood-Buff fluctuation relations. On the other hand, Monte Carlo simulations show that both the effective pair potentials and the correlation functions are accurately predicted by the RJM. It is suggested that the lack of self-consistency in the thermodynamics of the RJM is a result of neglected electrostatic correlations between the counterions and coions.en
dc.format.mimetypeapplication/pdfpt_BR
dc.language.isoengpt_BR
dc.relation.ispartofThe journal of chemical physics. New York. Vol. 136, no. 19 (May 2012), 194103, 7 p.pt_BR
dc.rightsOpen Accessen
dc.subjectEquações de estadopt_BR
dc.subjectColóidespt_BR
dc.subjectSuspensoespt_BR
dc.subjectMétodo de Monte Carlopt_BR
dc.subjectJelliumpt_BR
dc.subjectTermodinâmicapt_BR
dc.titleEquation of state of charged colloidal suspensions and its dependence on the thermodynamic routept_BR
dc.typeArtigo de periódicopt_BR
dc.identifier.nrb000867599pt_BR
dc.type.originEstrangeiropt_BR


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