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dc.contributor.authorPasso, Joel Aparecidopt_BR
dc.contributor.authorMerlo, Aloir Antoniopt_BR
dc.contributor.authorEccher, Julianapt_BR
dc.contributor.authorBechtold, Ivan Helmuthpt_BR
dc.contributor.authorKelly, Stephen M.pt_BR
dc.date.accessioned2014-11-12T02:14:32Zpt_BR
dc.date.issued2012pt_BR
dc.identifier.issn0100-4042pt_BR
dc.identifier.urihttp://hdl.handle.net/10183/106750pt_BR
dc.description.abstractFive monomers 5-[4-(5-cyano-4,5-dihydroisoxazol-3-yl)phenoxy]undecyl acrylate (7a); n-alkyl 3-{4-[5-(acryloyloxyundecyl) oxyphenyl]}-4,5-dihydroisoxazole-5-carboxylate (7b,c for n-butyl and n-hexyl, respectively); 3-{4-[5-(acryloyloxyundecyl) oxyphenyl]}-4,5-dihydroisoxazole-5-carboxylic acid (7d) and (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl acrylate (9) and the corresponding copolymers 10a-d, 11 and homopolymers 12 from 7a and 13 from 9 were designed and synthesized. Except for acrylate 9 which is derived from (-)-menthol, all of the monomers belong to the series containing the isoxazoline ring linked to the acrylate unit by a flexible spacer chain of eleven methylene units. They presented low glass temperature and despite birefringence behavior, these copolymers showed no mesomorphic properties.en
dc.format.mimetypeapplication/pdf
dc.language.isoporpt_BR
dc.relation.ispartofQuímica nova. São Paulo. Vol. 35, n. 8 (2012), p. 1527-1533pt_BR
dc.rightsOpen Accessen
dc.subject3,5-disubstituted isoxazolinesen
dc.subjectQuímica macromolecularpt_BR
dc.subjectCopolymersen
dc.subjectCopolímeros : Caracterizaçãopt_BR
dc.subjectMenthyl acrylateen
dc.titleSíntese e caracterização de copolímeros de cadeia lateral derivados de acrilatos de 4,5-di-hidroisoxazol e do (-)-mentolpt_BR
dc.typeArtigo de periódicopt_BR
dc.identifier.nrb000937860pt_BR
dc.type.originNacionalpt_BR


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